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By F.E. Bailey

A finished remedy of a giant family members of polymers important in quite a lot of purposes in such fields as car, pharmaceutical, beauty, metal-working, mining, business coating, cloth, development, and residential furniture. Summarizes the chemistry and mechanisms; presents simple prepa

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Extra resources for Alkylene Oxides and Their Polymers

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62:2599 (1940). Page 33 10. R. Fordyce, E. L. Lovell, and H. Hibbert, J. Amer. Chem. Soc. 61:1905 (1939). 11. P. J. Flory, J. Amer. Chem. Soc. 62:1561 (1940). 12. P. A. Levene and A. Walti, J. Biol. Chem. 75:325 (1927). 13. I. G. Farbenindustrie, A. S. Patent Nos. 1,921,378, 1,922,918, and 1,976,678. 14. P. H. Schlosser and K. R. S. Patent No. 2,362,217 assigned to Rayonnier, Inc. 15. H. R. Rife and F. H. S. Patent Nos. 2,448,664 (1948); 2,520,612 (1950). 16. W. J. Toussaint and H. R. S. Patent No.

D. Clayton and F. E. Clayton, Patty's Hygiene and Toxicology, V2B, Toxicology, John Wiley & Sons, New York, 1981, p. 3109. Page 25 8. K. M. :78–83 (October 1988). 9. A. Phatak, C. M. Burns, and R. Y. N. Huang, J. Appl. Polymer Sci. 34:1835 (1987). 10. T. L. Caskey, Mod. Plastics 45:148 (1967). 11. Imperial Chemical Ind. , The Handling and Storage of Ethylene Oxide, CPP4, The Chemical Industries Safety & Health Council of the Chemical Industries Association, London, August 1975. 12. G. D. Clayton and F.

Staudinger had pointed out to them that ethylene oxide in the presence of small amounts of catalysts such as potassium, tin tetrachloride, and trimethylamine can occasionally polymerize completely in a few seconds at ordinary temperatures. Since the large heats of reaction caused explosive destruction of the reaction tubes, and because ethylene oxide was used in large amounts at I. G. Farbenindustrie, an investigation of ethylene oxide in the presence of different materials, and particularly iron and iron compounds, was undertaken.

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